Excess Molar Volume for Cyclohexanone (C6H10O) with Chloroalkanes at 303.15K
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Excess Molar Volume for Cyclohexanone (C6H10O) with Chloroalkanes at 303.15K
1Atri D. Tripathi* and 2Souvik Sur
Original Article
Bulletin of Pure and Applied Sciences.
Chemistry , Vol.42 C, No.1
January-June 2023: P.9-13
DOI: 10.48165/bpas.2023.42C.1.2
Description
Description
Excess Molar Volume for Cyclohexanone (C6H10O) with Chloroalkanes at 303.15K
1Atri D. Tripathi* and 2Souvik Sur
Author Affiliations
1Department of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
2Research and Development Center, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
*Corresponding Author
Atri D. Tripathi, Department of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India
E-mail: atri34tmu@gmail.com
Received on 27.12.2022, Revised on 07.02.2023, Approved on 23.02.2023, Accepted on 31.03.2023, Published on 20.06.2023
Abstract
ABSTRACT
Measurements on excess molar volume by using dilatometer have been made for mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, Chloroform and 1,3 dichloropropane at 303.15K and under atmospheric pressure in the liquid state. The obtained data have been fitted with the help of polynomial Redlich-Kister equation and discussed with the point view of molecular interactions in the liquid state. The values of VE have been found to be negative in sign for the mixtures of Cyclohexanone with 1-chlorobutane, acetylene tetrachloride, and chloroform whereas it is positive in sign with 1,3-dichloropropane. The results obtained may be attributed to donor-acceptor interaction for all components in the liquid state.
Keywords: Excess Volume, Cyclohexanone, Interaction, H-bonding, Physicochemical Properties
